Foundations in Chemistry

This bundle is ideal for classroom or home learning and covers the whole of the OCR A level chemistry specification module 2 - Foundations in Chemistry, sections 2.1 and 2.2.
Each topic includes a fully interactive PowerPoint including starter, group activities, questions and plenary along with a worksheet and a lesson plan. Answers to all exercises are provided. Some of the resources include a PowerPoint quiz. A practical activity on titration is also included.

This bundle relates to the following sections of the OCR AS Chemistry specification:
Module 2 – Foundations in chemistry
Part 1 – Atoms and reactions (whole)
2.1.1 – Atomic structure and isotopes
2.1.2 – Compounds, formulae and equations
2.1.3 – Amount of substance
2.1.4 – Acids
2.1.5 − Redox
Part 2 – Electrons, bonding and structure (whole)
2.2.1 – Electron structure
2.2.2 – Bonding and structure
Module 3 – The Periodic table and energy
Part 1 –The Periodic Table (part)
3.1.1 (Periodicity) (part)

Content covered:

The changing atom
How Science Works - HSW7 - The changing accepted models of atomic structure over time.
The contributions of five scientists to the development of the theory of atomic structure.

Atomic structure
• Protons, neutrons and electrons – mass and relative charge
• Atomic number and mass number
• Isotopes
• Key definitions

Atomic masses
• Relative masses - comparison of masses to carbon-12
• Calculating relative atomic mass from the masses and abundances of the isotopes
• Mass spectrometry and its use in the above
• Calculating relative molecular and relative formula masses from formulae
• Key definitions of relative atomic mass and relative isotopic mass

Formulae and equations
• Formulae of ions
• Predicting ionic charges from the Periodic Table
• Writing the formulae of ionic compounds and elements
• Writing and balancing equations
• Common types of reaction and their equations

Amount of substance and the mole
• Relative masses and the mole
• Avogadro constant
• Calculating number of atoms
• Amount of substance
• Molar mass
• Calculating amount of substance from total mass and vice versa
• Mole triangle

Determining formulae
• Definitions and use of the terms empirical and molecular formula
• Simplest whole number ratios
• Calculations of empirical and molecular formulae, from composition by mass or percentage compositions by mass and relative molecular mass
• Calculating % by mass from the formula
• The terms anhydrous, hydrated and water of crystallisation
• Calculation of the formula of a hydrated salt from given percentage composition, mass composition or based on experimental results

Moles and gas volumes
• Molar volume of a gas
• Moles and gas volume triangle
• Summary of relationships for gases between amount of substance, volume, mass and number of molecules
• Calculating amount of substance from volume of gas and vice versa
• Ideal gases
• The ideal gas equation

Moles, concentrations and solutions
• Definitions and use of the terms concentration and mass concentration
• Concentrated and dilute
• Relationship between concentration, amount in mol and volume including concentration triangle
• Calculating concentration, amount in mol, volume and mass from given data
• Example calculations
• Mass concentrations
• Choosing the correct glassware to measure volumes
• Standard solutions
• Practical activity – making up a standard solution
• Diluting solutions and calculations
• Practical activity – diluting solutions

Moles and reactions
• Balanced chemical equations and stoichiometry
• Molar ratios
• Using molar ratio to calculate amounts in moles of reactants and products in a chemical reaction
• Using molar ratio to calculate masses of reactants and products in a chemical reaction
• Using molar ratio to calculate volumes of gases in a chemical reaction
• Flow diagrams showing steps in calculations involving quantities of reacting substances
• Example calculations – clearly illustrated in a highly visual way

Percentage yield and atom economy
• Introduction to Green Chemistry
• Reasons why reactions do not have 100% yield
• % yield and how to calculate it
• Calculations of % yield involving limiting reactant
• Atom economy and its importance in the sustainability of a chemical process
• Calculating atom economy
• Example calculations – clearly illustrated in a highly visual way
• Differences between atom economy and % yield
• Comparing chemical processes in terms of sustainability (using production of ethanol as an example)

Acids and bases
• Definitions of acid, base, alkali and salt
• Formulae of acids, bases, alkalis and salts
• The relationship between bases and alkalis
• The pH scale
• Everyday examples of acids and bases
• Weak and strong acids
• Diprotic acids
• Writing and balancing neutralization reactions (including acid-carbonate reactions)
• Ionic equations

Acid-base titrations
• Titration and uses
• Standard solution
• Glassware and procedure for titration with detailed hints for technique
• Reading burette
• Recording titration results and calculating the mean
• Titration calculations
• Examples of structured and unstructured calculations
• Revision of calculations involving masses and volumes
• Practical titration activity
• Evaluation of titration experiment
• Uncertainties and calculating % uncertainties
• Procedural errors

Redox
• Redox definition in terms of electron transfer
• Oxidation numbers and how to calculate them
• Oxidation number in chemical names
• Redox definition in terms of oxidation number
• Using oxidation numbers to identify redox reactions and determine what has been oxidised and reduced
• Oxidising and reducing agents
• Disproportionation as oxidation and reduction of the same element

Electron configuration - shells, sub-shells and orbitals
• Energy levels
• Main shells, sub-shells and orbitals
• Rules for filling orbitals
• Electron configurations of atoms and ions
• Deducing electron configuration using the Periodic Table
• Relationship of electron configuration to the Periodic Table

Ionic bonding
• Bonding and the Periodic Table
• Predicting ionic formulae
• Definition of ionic bonding
• Dot-and-cross diagrams – some of them animated
• Half equations
• Giant ionic lattice
• Physical properties of ionic compounds including:
• melting point
• electrical conductivity
• solubility in polar and non-polar solvents

Covalent bonding
• Definition of a covalent bond
• Single, double and triple covalent bonds
• Lone pairs
• How to construct dot-and-cross diagrams
• Dative covalent or coordinate bonds
• The Octet Rule and exceptions
• Average bond enthalpies

Shapes of molecules and ions
• Electron pair repulsion theory (VSEPR)
• Effect of lone pairs on shape
• Model answer to exam question
• How to draw simple shapes in 3D
• Bond angles

Electronegativity and bond polarity
• Definition of electronegativity
• Atomic core and calculation of core charge
• Factors affecting electronegativity
• Pauling scale of electronegativity
• Electronegativity and bond polarity
• Non-polar and polar covalent bonds
• Electronegativity and bonding type (including intermediate bonding)
• Polarity of molecules from the bond polarities and the molecular shape
• Predicting whether a molecule will have an overall dipole from its symmetry

Intermolecular forces
• What are intermolecular forces?
• Strengths of bonds and intermolecular forces
• Types of intermolecular forces
• Induced dipole-dipole interactions (London (dispersion) forces)
• How London forces arise
• Factors affecting strength of London forces
• Permanent dipole-dipole interactions
• How permanent dipole-dipole interactions arise
• How intermolecular forces affect properties
• Hydrogen bonding
• What’s special about hydrogen bonds
• Effects of hydrogen bonds on properties
• Special properties of water
• Summary of intermolecular forces
• Predicting the type of intermolecular forces

Structure and bonding
• Factors influencing physical properties
• The way the atoms/ions are grouped together (structure)
• The type of particles the solid is built up from
• The bonds or forces holding these particles together
• Structure and physical properties of ionic compounds (see also topic 15)
• Structures and physical properties of covalent substances including giant covalent and simple molecular
• Diamond and graphite – structures and properties
• Graphene
• Metallic bonding, structure and physical properties
• Summary of types of bonding
• Jigsaw discussion to summarise 4 main types of structure and their properties

Links
Next lesson – free resource: Topic 21 – the Periodic Table past and present
http://www.tes.com/teaching-resource/periodic-table-past-and-present-ocr-as-chemistry-12964450